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RAS Chemistry & Material ScienceЖурнал аналитической химии Journal of Analytical Chemistry

  • ISSN (Print) 0044-4502
  • ISSN (Online) 3034-512X

IONIC LIQUIDS AS PROMISING FUNCTIONAL MATERIALS FOR MICROEXTRACTION OF STEROID HORMONES

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PII
S0044450225080023-1
DOI
10.31857/S0044450225080023
Publication type
Article
Status
Published
Authors
A. T. Araslanova
  • Affiliation:
    Saint Petersburg State University
    Institute of Chemistry
Volume/ Edition
Volume 80 / Issue number 8
Pages
782-797
Abstract
Prospects for the use of imidazolium ionic liquids (IL) as extractants of sex steroid hormones (estrogens and androgens) in microextraction methods (dispersive liquid-liquid microextraction, DLLME, and magnetic solid-phase microextraction, mSPME) are identified. The key parameters of DLLME using CMImNTf IL, affecting the extraction efficiency, are optimized using the design of experiment method. High degrees of recovery (88–99 %) are achieved. An approach of dynamic IL immobilization on the surface of magnetic nanoparticles (MNPs) for steroid extraction under mSPME conditions is proposed. Two types of MNP pre-coating are studied: hydrophilic based on silica and hydrophobic with oleic acid. The capabilities of CMImBF IL as a MNP surface modifier for efficient steroid extraction are revealed. Optimum conditions provided high degrees of recovery (83–97 %), with the exception of estriol (60 %). The detection limits are 0.26–1.29 ng/mL. Limitations of the method related to partial removal of IL from the surface of NPs are revealed, which reduces the reproducibility of the results for estriol.
Keywords
ВЭЖХ с диодно-матричным детектированием половые стероидные гормоны дисперсионная жидкостно-жидкостная микроэкстракция магнитная твердофазная микроэкстракция ионные жидкости
Date of publication
14.09.2025
Year of publication
2025
Number of purchasers
0
Views
14

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